When we studied physics in school, we learned that pure, distilled
water (H2O) is an insulator. In real life, however, tap water is never
clean. It is full of salts, minerals and trace elements which turn the
water into an excellent conductor of electricity.
What happens if you throw a glass or bucket of water on a burning TV
that is plugged in?
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The solid "column" of water that leaves your hand and hits
the device creates a bridge.
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The device's 230V current finds its way out, travels instantaneously
through the water in the air, reaches your wet hand, passes through
your heart, and ends up on the floor.
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The result is not just the spread of fire (as sparks will fly
everywhere), but a fatal electric shock to the one who threw the
water.
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Note: The same applies to Foam or Water extinguishers. It is
strictly forbidden to use them with electricity.